Hello! This is the person who uploaded all the Hetalia episodes to LJ. You have your settings set so that I can't send you a message, so I'll leave my reply here:

All the episodes should all have subs, but I might have accidentally uploaded the wrong version. Which link did you download the episode from? I'll fix it as soon as I can (though I'm about to leave, so it won't be up until later tonight).

I'm so glad that this list is able to help you get into the fandom! I think you'll find that the Hetalia fandom is one of the most friendly fandoms out there, so I really hope you have a good time here!

-Crystal